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Catalogue Number:C984570
Chemical Name:1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate
Synonyms:(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(1+) hexafluorophosphate; (1,5-Cyclooctadiene)pyridine(tricyclohexylphosphine)iridium hexafluorophosphate; (η4-1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate; Crabtree's Catalyst; Felkin-Crabtree catalyst;
CAS Number:64536-78-3
Molecular Formula:C₃₁H₄₈F₆IrNP₂
Appearance:Orange Solid
Melting Point:>137ºC (dec.)
Molecular Weight:802.88
Storage:4°C, Hygroscopic
Solubility:Chloroform (Slightly)
Category:Building Blocks; Catalyst;
Applications:1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate is a catalyst that is used in the synthesis of 4a,5-Dihydro Simvastatin (D450010). 4a,5-Dihydro Simvastatin is an impurity in the synthesis of Simvastatin (S485000), a synthetic derivative of a fermentation product of Aspergillus terreus. A competitive inhibitor of HMG-CoA reductase. A synthetic analog of Lovastatin. Antilipemic. Simvastatin, the drug, is sold under the trade name Zocor.
References:Hoffman, W.F., et al.: J. Med. Chem., 29, 849 (1986), Mol, M.J., et al.: Lancet, 2, 936 (1986),
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